A P-plate driver was caught by police driving at 191 kilometres per hour in a 110 kilometres-per-hour zone, with two children in the car.

The 19-year-old man was speeding on the Hume Highway near Jugiong in the NSW Riverina area when he was pulled over by police.

Two children aged one and three were in the back seat of the car, while their mother was in the front passenger seat.

The driver from Cootamundra was charged with a range of speeding offences and his licence was suspended.

He is due to face Gundagai Local Court in May.