Two drivers have been stung speeding at up to 191km/h on the Hume Highway in the same BMW within two hours of each other.

NSW highway patrol officers said they spotted the BMW four-wheel-drive travelling at 166km/h on the Hume Highway at Kyeamba, near Tarcutta, about 10pm on Monday.

Its 29-year-old male driver was hit with a traffic infringement notice for exceeding the speed limit by more than 45km/h, and had his licence instantly suspended for six months.

The car was first detected speeding at Tarcutta, then pulled over two hours later after speeding through Coolac and Bookham.

His female passenger jumped in the driver’s seat and the pair continued their journey but only an hour and a half later, police received reports of a BMW travelling at high-speed on the Hume Highway at Coolac and Bookham.

A 24-year-old woman in the same BMW was pulled over at Yarra shortly after midnight after police detected the car travelling at 191km/h.

It was later revealed her licence was suspended.

She was issued a field court attendance notice for driving in a dangerous manner, exceeding the speed limit by more than 45km/h, and driving while suspended.

She is expected to appear before Goulburn Local Court on Tuesday, March 22.

The car was taken to Goulburn, where the man and woman were forced to make alternate travel arrangements, NSW Police said.